Hydride Reduction | NaBH4 vs LiAlH4 vs DIBAH | 20.5 Organic Chemistry
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Chad provides a succinct lesson covering a few select reductions using special hydride reagents. Specifically, the reduction of acid halides and acid anhydrides to aldehydes using lithium tri-tert-butoxyaluminum hydride and the reduction of esters to aldehydes using DIBAH (di-isobutylaluminum hydride).
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00:00 Lesson Introduction
00:36 NaBH4 Reduction of Acid Halides and Acid Anhydrides
03:42 LiAlH4 Reduction of Acid Halides, Anhydrides, Carboxylic Acids, and Esters
06:24 LiAlH4 Reduction of Amides and Nitriles
08:05 Reductions with Lithium Tri-tert-butoxyaluminum Hydride and DIBAH (a.k.a. DIBAL-H)
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